Technology of LIBS Imaging

Nordic LIBS 2024 slides
available at libsimaging.net/nordiclibs2024
Poster=handout is available

Tampere, March 2024


Ilkka Laine
ilkka.laine@aalto.fi

Technology of LIBS Imaging

1 Context

2 LIBS Imaging devices 1: LIBS-LIDAR

3 LIBS Imaging devices 2: LASOLIBS

4 Spectral analysis simply

5 LIBS resources and tools to share

Context

  • Me:
    Automation engineer building LIBS scanners -> LIBS Imaging researcher

  • Research goal:
    Give you the tools to do LIBS imaging and explain it clearly

LIBS

Laser-Induced Breakdown Spectroscopy or Laser spark spectroscopy.

Laser -> spark -> emission spectrum -> elemental content


Imaging means doing many measurements over an area for pretty pictures.

LIBS Imaging Devices 1: LIBS-LIDAR Tunnel Wall Scanner

For remote measurements from 3 to 8 meter distance. Was built to scan mine tunnel walls from safe distance.

LIBS Imaging Devices 2

Large Area Scanning Open-Source LIBS (LASOLIBS)

Scans boxes of drill core or any other samples that fit on a table.
LASOLIBS (Video)

A commercial version by Lumo Analytics is used in multiple mine and ore exploration sites in Finland and USA.

LASOLIBS parts

  • 3D-printer like frame to move measurement head, built of MakerSlide
  • Measurement head, 3d printed parts
    • Laser (1000Hz)
    • Autofocus with Position Sensitive Detector(PSD)
  • Spectrometer
  • Teensy microcontroller running Arduino code
  • Cost of parts ~10000 euros for a DIY person.








































LIBS Analysis Methodology Simply

From Spectra to results
Spectrum -> Identify elemental peaks with reference list -> Measure peak heights -> Compare them

LIBS Analysis Methodology With computer

Simple elemental heatmaps by selecting a channel with an elemental peak.

Spectral Angle Mapping(SAM) compares similarity of two measurements. Great for classifying materials/minerals to a reference.

Resources 1: spectra

Peaks

All elemental peaks from NIST ASD scraped into convenient excel files.

Elemental library

Experimental LIBS spectra of many elements, soon including a full set of REE elements.

Mineral library

Experimental LIBS spectra of mineral collections.

Will be available from libsimaging.net (sry not yet) and uploaded to Zenodo.

Resources 2: LIBS imaging demos

I'm happy to do a LIBS imaging demo if you send me a sample.

Thanks!

Ilkka Laine
Aalto University
ilkka.laine@aalto.fi
+358 50 490 5909

These slides are available at libsimaging.net/nordiclibs2024

Extra slides:

Contacts

Resources 3: tools

Contacts

Resources 3: tools

For commercial geological/mining projects
Lumo Analytics
info@lumoanalytics.com

For research related or any other inquiries
ilkka.laine@aalto.fi (me)
+358 50 490 5909

Resources 3: tools

Analysis tools software library

Free software tools available!

  • MATLAB and Julia scripts

Hyperspectral tools work with LIBS data often as well.

Acknowledgements

Showing work of among others:
Lasse Kangas, Jussi Leveinen, Henri Johansson, Tuure Takala, Luis Huaman

Thanks!

Ilkka Laine
Aalto University
ilkka.laine@aalto.fi
+358 50 490 5909

These slides are available at libsimaging.net/nordiclibs2024

![bg invert right:40%](libs_imaging.jpg) Good afternoon fellow LIBS enthusiasts! I am Ilkka Laine from Aalto University from Helsinki. Today I will take you through the my story with LIBS Imaging. I have a poster out there as well if this looks familiar. I put my slides and the poster available on the internet on libsimaging.net slash nordiclibs2024.

Here is an outline of what I will talk about. So first is context about my background. Second I'll show you two different LIBS imaging devices, LIBS scanners that we have built at Aalto University. This is the main content of my presentation. Then we look into the LIBS images made with these and couple methods for analysis. And lastly I mention some LIBS resources and databases I want to share with you. First about me for context.

I'm an automation engineer turned LIBS Imaging researcher. I started building LIBS scanners at Aalto University in 2018 and currently my research goal is to give all of you the tools needed to do LIBS Imaging analysis and explaining it as simply as possible.

I'm believe the fundamentals are most important so we are not gonna skip this. What is LIBS? LIBS stands for Laser-Induced Breakdown Spectroscopy, but I find its old name, Laser Spark Spectroscopy is much better name when explaining it to someone. In Laser Spark Spectroscopy we shoot laser to do a spark on the sample and then collect the light of the spark to a spectrometer. The wavelengths of the light reveal all elements and some molecules present in the sample. Imaging means doing many measurements over an area for pretty pictures. With "Many" I mean ten thousand, hundred thousand or millions of measurements. LIBS has been done since laser was invented in the 60s, but LIBS imaging has become prominent only recently. So what's the trick? The trick is doing it fast, cheap, reliably and being capable of measuring any shape samples. So combining cheap, small and fast lasers and spectrometers with the computers controlled frame similar to 3D printers or CNC machines, we get a LIBS scanner.

LIBS-LIDAR We demonstrated this in mine conditions Kittilä gold mine But compared to the convenient table size scanner, this device is dangerous, heavy and expensive so it was left as a prototype, for now. A few years ago I was recruited to Aalto University to build a LIBS-LIDAR, a remote LIBS scanner that can map rock walls and tunnel endings from a safe distance with LIBS. Most of you probably know the CHEMCAM LIBS instrument in the Mars rovers. Our idea was to bring this technology back to earth. We built this device with adaptive focusing and receiving optics During the project my collegue started to work on another LIBS scanner device, a drill core scanner.

This is our main tool. Large Area Scanning Open-source Laser-Induced Breakdown Spectrometer or LASOLIBS. It was designed to scan drill cores one box at at time but can be used to scan any shape samples that fit in the device. We work mainly with geological samples so that means rocks mostly. I will show a little video if that works. The device is this 3-axis frame similar to 3D printers that moves the LIBS measurement head over the sample. It has autofocus to make consistent sparks on any shape samples and can do up to thousand measurements per second and move the measurement head half a meter per second. As a side note, the original plan for this design was to publish the building instructions as free and open hardware for anyone to build this by themselves. I still hope to publish them some day but so far the instructions are not finished, as my colleague and the main guy behind this device Lasse Kangas went to start a company Lumo Analytics in Helsinki that does these commercially and so successfully that he doesnt have any extra time.

![bg](whole_LASO_cropped.jpg)

A little invention we made while building this device is our autofocus method which is a cheap an simple method. We have a position sensitice detector PSD set behin Pros: cheap and easy to build

## LIBS Images 1: Drill cores

## LIBS Images high resolution HIGHRES LIBS images This is a scan from a piece of drillcore so a small piece of rock, about 3 x 4 centimeter area. On the left is xx and on the right is yy. So our device can do both large areas quickly. Scanning a box takes depending on the wanter resolution from minutes to couple hours.

## LIBS Images high resolution

## LIBS Images: Hand sample

LIBS Analysis Methodology Simply. Methodology simple enough you can do it with pen and paper and a book of the peaks

Spectral Angle Mapper(SAM) is an essential

Thanks! And qustions please

+358 50 581 6319 (Lumo CEO Antti Kotanen)

Thanks! And qustions please

previous draft versions: edellinen: I work at Aalto Civil Engineering department building Laser-Induced Breakdown Spectroscopy(LIBS) scanners and developing LIBS imaging with mining industry. I came to Nordic LIBS 2024 to share with you what we can do with this technology. To present the very basics of LIBS imaging to give you a clear image of what it is. Cons: need to keep libs laser on to autofocus. ## LIBS Imaging Devices ### LASOLIBS Autofocus system Autofocus using position sensitive detector(PSD) with LIBS laser as light source.